DL-Malic acid
SIGMA/27606 - meets analytical specification of FCC, E296, 99-100.5% (alkalimetric)
Synonym: (±)
CAS Number: 6915-15-7
Empirical Formula (Hill Notation): C4H6O5
Molecular Weight: 134.09
EC Number: 230-022-8
MDL Number: MFCD00064212
Linear Formula: HO2CCH2CH(OH)CO2H
Product Type: Chemical
application(s) | pharmaceutical (small molecule) |
assay | 99-100.5% (alkalimetric) |
autoignition temp. | 644 °F |
cation traces | As: ≤3 mg/kg |
Hg: ≤1 mg/kg | |
Pb: ≤2 mg/kg | |
form | solid |
ign. residue | ≤0.1% (as SO4) |
impurities | ≤0.05% maleic acid |
≤0.1% water insoluble matter | |
≤1% fumaric acid | |
InChI | 1S/C4H6O5/c5-2(4(8)9)1-3( |
InChI key | BJEPYKJPYRNKOW-UHFFFAOYSA |
mp | 129-133 °C |
131-133 °C (lit.) | |
optical activity | [α]/D −0.10 to +0.10° |
quality | meets analytical specification of FCC, E296 |
Quality Level | 200 |
SMILES string | OC(CC(O)=O)C(O)=O |
solubility | acetone: soluble 17.75 g/ 100 gm at 20 °C |
benzene: insoluble | |
diethyl ether: soluble 0.84 g/100 gm at 20 °C | |
dioxane: soluble 22.70 g/100 gm at 20 °C | |
ethanol: soluble 45.53 g/100 gm at 20 °C | |
methanol: soluble 82.70 g/100 g at 20 °C | |
water: soluble 55.8 g/100 gm at 20 °C | |
suitability | complies for identity (IR) |
technique(s) | IR spectroscopy: suitable |
vapor density | 4.6 (vs air) |
vapor pressure | <0.1 mmHg ( 20 °C) |
Application: | DL-Malic acid is an organic acid used for studying the impact on ultrasound pasteurization. It has also been used to culture Pichia membraneafaciens. |
Biochem/physiol Actions: | Malic acid is a dicarboxylic acid and an important regulatory metabolite. It has been implicated in process of fruit ripening. Malic acid is important for the starch metabolism; low malic acid content results in transient accumulation of starch. Mitochondrial-malate metabolism modulates ADP-glucose pyrophosphorylase activity and redox status of plastids. |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H319 |
Precautionary statements | P264 - P280 - P305 + P351 + P338 - P337 + P313 |
Hazard Codes | Xi |
Risk Statements | 36 |
Safety Statements | 26 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | 397.4 °F |
Flash Point(C) | 203 °C |
Purity | 99-100.5% (alkalimetric) |
mp | 129-133 °C; 131-133 °C (lit.) |
UNSPSC | 12352106 |