Synonym: (4S,5R)-4,5-Dihydroxy-2-oxo-6-phosphonooxyhexanoic acid lithium salt; 2-Dehydro-3-deoxy-6-phospho-D-gluconate lithium salt; 2-Keto-3-deoxy-6-phosphogluconate lithium salt; 3-Deoxy-2-keto-D-gluconic acid 6-phosphate lithium salt; 3-Deoxy-D-erythro-hexulosonic acid 6-phosphate lithium salt; KDPG
CAS Number: 27244-54-8 (free acid)
Empirical Formula (Hill Notation): C6H11O9P · xLi+
Molecular Weight: 258.12 (free acid basis)
Linear Formula: C6H11O9P · xLi+
Product Type: Chemical
assay |
≥95% (TLC) |
color |
white |
form |
powder |
InChI |
1S/C6H11O9P/c7-3(1-4(8)6(10)11)5(9)2-15-16(12,13)14/h3,5,7,9H,1-2H2,(H,10,11)(H2,12,13,14)/t3-,5+/m0/s1 |
InChI key |
OVPRPPOVAXRCED-WVZVXSGGSA-N |
optical activity |
[α]/D 9.0±1.0°, 3 hr, c = 0.1 in H2O |
Quality Level |
100 |
storage temp. |
−20°C |
Biochem/physiol Actions: |
2-dehydro-3-deoxy-phosphogluconate is a substrate for the enzyme 2-dehydro-3-deoxy-phosphogluconate aldolase which converts it into D-glyceraldehyde 3-phosphate plus pyruvate. |
Biochem/physiol Actions: |
Metabolite in the pentose phosphate pathway, generating NADPH and pentoses; and in the in pentose and glucuronate interconversions; key intermediate in the Entner-Doudoroff pathway of some bacteria, substrate of 2-Keto-3-deoxy-6-phosphogluconate (KDPG) aldolase, catalyzing the reversible cleavage of KDPG to pyruvate and glyceraldehyde-3-phosphate. It was found to be the carbon catabolite repression signal of phenylacetic acid metabolism in P. putida KT2440. Expression from Pu was repressed mainly via PtsN in response to high levels of 2-dehydro-3-deoxygluconate-6-phosphate. |
Other Notes: |
To gain a comprehensive understanding of our extensive range of Monosaccharides for your research, we encourage you to visit our Carbohydrates Category page. |
Packaging: |
Bottomless glass bottle. Contents are inside inserted fused cone. |
RIDADR |
NONH for all modes of transport |
WGK Germany |
WGK 3 |
Flash Point(F) |
Not applicable |
Flash Point(C) |
Not applicable |
Purity |
≥95% (TLC) |
Storage Temp. |
−20°C |
UNSPSC |
12352201 |